In a medium bowl, combine the soy sauce, vinegar, water, 1 tablespoon olive oil, crushed red pepper, and garlic. Add the pork chops and marinate them in refrigerator for 20 minutes or longer.

Steam the broccoli for 5 minutes; until tender.

Add the remaining 2 tsp olive oil to a large sauté pan over medium-high heat. Add the pork chops and sear for about 5 minutes per side or until done. (Reserve marinade for later).